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Solutions



Multiple Choice
Identify the letter of the choice that best completes the statement or answers the question.
 

1. 

Which of the following has components that are obviously different?
a.
homogeneous mixture
c.
colloid
b.
solution
d.
heterogeneous mixture
 

2. 

A heterogeneous mixture always contains
a.
only one substance.
b.
more than two substances.
c.
two or more substances that are visibly distinguishable.
d.
two or more substances that are not visibly distinguishable.
 

3. 

Which of the following is a pure substance?
a.
water
c.
soil
b.
milk
d.
concrete
 

4. 

Which of the following is a heterogeneous mixture?
a.
water
c.
whole-wheat bread
b.
a sugar-water solution
d.
sugar
 

5. 

Which of the following is a homogeneous mixture?
a.
water
c.
whole-wheat bread
b.
a sugar-water solution
d.
sugar
 

6. 

Which of the following is a thoroughly mixed homogeneous mixture of substances in a single phase?
a.
a solution
c.
a compound
b.
a colloid
d.
a suspension
 

7. 

All of the following are homogeneous mixtures EXCEPT
a.
sodium chloride.
c.
gasoline.
b.
a sugar-water solution.
d.
a salt-water solution.
 

8. 

All of the following are heterogeneous mixtures EXCEPT
a.
whole-wheat bread.
c.
tap water.
b.
granite.
d.
an oil-water mixture.
 

9. 

Which of the following is NOT a solute-solvent combination?
a.
gas-gas combination
c.
gas-solid combination
b.
gas-liquid combination
d.
liquid-solid combination
 

10. 

Water in air is an example of which solute-solvent combination?
a.
gas-liquid
c.
liquid-liquid
b.
liquid-gas
d.
gas-gas
 

11. 

Carbon dioxide in water is an example of which solute-solvent combination?
a.
gas-liquid
c.
liquid-liquid
b.
liquid-gas
d.
cannot be determined
 

12. 

Sugar in water is an example of which solute-solvent combination?
a.
gas-liquid
c.
solid-liquid
b.
liquid-liquid
d.
liquid-solid
 

13. 

Oxygen in nitrogen is an example of which solute-solvent combination?
a.
gas-liquid
c.
gas-solid
b.
liquid-gas
d.
gas-gas
 

14. 

Which mixture contains visible particles that settle out unless the mixture is stirred?
a.
a colloid
c.
a solution
b.
a homogeneous mixture
d.
a suspension
 

15. 

Which mixture contains particles that are in a dispersed phase and do not settle out?
a.
a colloid
c.
a solution
b.
a heterogeneous mixture
d.
a suspension
 

16. 

A metal solution is a(n)
a.
colloid.
c.
suspension.
b.
alloy.
d.
electrolyte.
 

17. 

An aerosol dispenser contains a colloidal dispersion of
a.
two liquids.
c.
a solid and a liquid.
b.
two solids.
d.
a gas and a liquid.
 

18. 

The colloidal particles in a colloid form the
a.
dispersing medium.
c.
solvent.
b.
dispersed phase.
d.
solute.
 

19. 

Colloids
a.
can be separated by filtering.
c.
scatter light.
b.
settle out when allowed to stand.
d.
are heterogeneous.
 

20. 

The Tyndall effect is used to distinguish between
a.
liquids and gases.
c.
colloids and heterogeneous mixtures.
b.
solutions and colloids.
d.
solvents and solutes.
 

21. 

A substance whose water solution conducts a current is a(n)
a.
nonelectrolyte.
c.
nonpolar substance.
b.
electrolyte.
d.
solute.
 

22. 

To conduct electricity, a solution must contain
a.
nonpolar molecules.
c.
ions.
b.
polar molecules.
d.
free electrons.
 

23. 

Which of the following is an electrolyte?
a.
sodium chloride
c.
water
b.
sugar
d.
glass
 

24. 

A substance whose water solution does NOT conduct a current is a(n)
a.
polar substance.
c.
electrolyte.
b.
nonelectrolyte.
d.
ionic substance.
 

25. 

Which of the following is a molecular substance whose water solution conducts electricity?
a.
liquid hydrogen
c.
sugar
b.
hydrogen chloride
d.
iron
 

26. 

Which of the following is a nonelectrolyte?
a.
sodium chloride
c.
sugar
b.
hydrogen chloride
d.
potassium chloride
 

27. 

Molecules whose water solutions conduct current
a.
require carbon to decompose in water.
c.
do not dissolve in water.
b.
ionize in water.
d.
can crystallize.
 

28. 

Which of the following does NOT increase the rate of dissolving a solid in water?
a.
raising the temperature
c.
using larger pieces of solid
b.
stirring
d.
crushing the solid
 

29. 

Increasing the surface area between solute and solvent
a.
increases the rate of dissolution.
b.
decreases the rate of dissolution.
c.
has no effect on the rate of dissolution.
d.
can increase, decrease, or have no effect on the rate of dissolution.
 

30. 

Which of the following decreases the average speed of solvent molecules?
a.
increasing the temperature
c.
adding more solvent
b.
stirring the solution
d.
decreasing the temperature
 

31. 

Stirring increases the rate of dissolution because it
a.
raises the temperature.
b.
lowers the temperature.
c.
brings fresh solvent into contact with the solute.
d.
decreases surface area of the solute.
 

32. 

Which of the following will dissolve most rapidly?
a.
sugar cubes in cold water
c.
powdered sugar in cold water
b.
sugar cubes in hot water
d.
powdered sugar in hot water
 

33. 

Which of the following will dissolve most slowly?
a.
large salt crystals in unstirred water
c.
small salt crystals in unstirred water
b.
large salt crystals in stirred water
d.
small salt crystals in stirred water
 

34. 

Raising the collision rate between solute and solvent
a.
increases the rate of dissolution.
b.
decreases the rate of dissolution.
c.
has no effect on the rate of dissolution.
d.
can increase, decrease, or have no effect on the rate of dissolution.
 

35. 

Raising solvent temperature causes solvent-solute collisions to become
a.
less frequent and more energetic.
c.
less frequent and less energetic.
b.
more frequent and more energetic.
d.
more frequent and less energetic.
 

36. 

If a solution is not agitated while it is being made, dissolved solute tends to
a.
mix uniformly.
c.
build up in the solvent near the solute.
b.
build up in the solvent far from the solute.
d.
raise the temperature of the solvent.
 

37. 

Which of the following is at equilibrium when undissolved solute is visible?
a.
a saturated solution
c.
a supersaturated solution
b.
an unsaturated solution
d.
all of the above
 

38. 

If the amount of solute present in a solution at a given temperature is less than the maximum amount that can dissolve at that temperature, the solution is said to be
a.
saturated.
c.
supersaturated.
b.
unsaturated.
d.
concentrated.
 

39. 

If the amount of dissolved solute in a solution at a given temperature is greater than the amount that can permanently remain in solution at that temperature, the solution is said to be
a.
saturated.
c.
supersaturated.
b.
unsaturated.
d.
diluted.
 

40. 

In a solution at equilibrium,
a.
no dissolution occurs.
b.
the rate of dissolution is less than the rate of crystallization.
c.
the rate of dissolution is greater than the rate of crystallization.
d.
the rate of dissolution and the rate of crystallization are equal.
 

41. 

The solubility of a substance at a given temperature can be expressed as
a.
grams of solute.
c.
amount of solute per amount of solvent.
b.
grams of solvent.
d.
grams of water per 100 g of solute.
 

42. 

The solubility of a solute depends on
a.
the nature of the solute and the temperature of the solvent.
b.
the nature of the solute only.
c.
the temperature of the solvent only.
d.
neither the nature of the solute nor the temperature of the solvent.
 

43. 

Which of the following is likely to produce crystals if disturbed?
a.
an unsaturated solution
c.
a saturated solution
b.
a supersaturated solution
d.
a concentrated solution
 

44. 

The rate of dissolution is
a.
directly related to solubility.
c.
related to the square of the solubility.
b.
inversely related to solubility.
d.
not related to solubility.
 

45. 

In the expression like dissolves like, the word like refers to similarity in molecular
a.
mass.
c.
energy.
b.
size.
d.
polarity.
 

46. 

The rule like dissolves like is used to predict
a.
solubility.
c.
reactivity.
b.
equilibrium.
d.
phase.
 

47. 

Which of the following is an example of a polar solvent?
a.
carbon tetrachloride
c.
water
b.
benzene
d.
gasoline
 

48. 

Which of the following is an example of a nonpolar solvent?
a.
water
c.
both a and b
b.
carbon tetrachloride
d.
neither a nor b
 

49. 

A substance that is NOT soluble in a polar solvent is
a.
nonpolar.
c.
polar.
b.
ionic.
d.
hydrogen bonded.
 

50. 

Which of the following is soluble in water?
a.
potassium nitrate
c.
benzene
b.
silver
d.
carbon tetrachloride
 

51. 

Sugar is soluble in water because sugar molecules are
a.
massive.
c.
nonpolar.
b.
large.
d.
polar.
 

52. 

Two immiscible substances are
a.
water and ammonia.
c.
carbon tetrachloride and benzene.
b.
water and ethanol.
d.
benzene and water.
 

53. 

Which of the following is a solvent for both polar and nonpolar solutes?
a.
water
c.
ethanol
b.
carbon tetrachloride
d.
benzene
 

54. 

Endothermic dissolution processes
a.
absorb heat and have positive heats of solution.
b.
release heat and have positive heats of solution.
c.
absorb heat and have negative heats of solution.
d.
release heat and have negative heats of solution.
 

55. 

In solvation, which particles interact?
a.
solute only
c.
solute and solvent
b.
solvent only
d.
none of the above
 

56. 

Which of the following releases energy?
a.
overcoming solute-solute attraction
c.
overcoming solvent-solvent attraction
b.
forming solute-solvent attraction
d.
all of the above
 

57. 

When the energy released by forming solvent-solute attractions is greater than the energy absorbed by overcoming solute-solute and solvent-solvent attractions, the dissolving process
a.
has a negative heat of solution.
c.
occurs rapidly.
b.
has a positive heat of solution.
d.
does not occur.
 

58. 

Increasing temperature favors dissolution when
a.
the heat of solution is negative.
c.
dissolution occurs rapidly.
b.
the heat of solution is positive.
d.
the dissolution process is exothermic.
 

59. 

The dissolution of gases in liquids is generally
a.
endothermic.
c.
rapid.
b.
exothermic.
d.
impossible.
 

60. 

Heat of solution is generally expressed in
a.
kilocalories.
b.
moles of solute per kilogram.
c.
kilojoules per mole of solute at a specified temperature.
d.
moles of solute in a specified amount of solvent per kilojoule.
 

61. 

Which of the following values for heat of solution at 25ºC represents the greatest release of energy?
a.
–3.59 kJ/mol
c.
+1.33 kJ/mol
b.
–0.01 kJ/mol
d.
+12.40 kJ/mol
 

62. 

The formation of solid-liquid solutions
a.
always releases heat.
c.
can either absorb or release heat.
b.
always absorbs heat.
d.
neither absorbs nor releases heat.
 

63. 

Pressure has the greatest effect on the solubility of
a.
solids in liquids.
c.
gases in gases.
b.
liquids in liquids.
d.
gases in liquids.
 

64. 

The solubility of gases in liquids
a.
always increases with increasing pressure.
b.
sometimes increases with increasing pressure.
c.
always decreases with increasing pressure.
d.
does not depend on pressure.
 

65. 

Henry's law relates
a.
pressure to temperature.
c.
temperature to gas-liquid solubility.
b.
pressure to gas-liquid solubility.
d.
pressure to liquid-solid solubility.
 

66. 

For a mixture of gases, the solubility of each gas in water varies
a.
directly with the partial pressure of the gas.
b.
inversely with the partial pressure of the gas.
c.
directly with the total pressure of the mixture.
d.
inversely with the total pressure of the mixture.
 

67. 

Effervescence is the
a.
dissolution of gas in liquid.
b.
escape of gas from a gas-liquid solution.
c.
escape of gas from a container of gas.
d.
escape of solid from a solid-liquid solution.
 

68. 

As temperature increases, solubility of gases in liquids
a.
increases.
c.
can increase or decrease.
b.
decreases.
d.
is not affected.
 

69. 

As temperature increases, solubility of solids in liquids
a.
always increases.
c.
usually increases.
b.
always decreases.
d.
usually decreases.
 

70. 

Cesium sulfate is a typical solid whose solubility decreases
a.
only if the pressure decreases.
c.
only if the pressure increases.
b.
with increasing temperature.
d.
with decreasing temperature.
 

71. 

Which of the following expresses concentration?
a.
molality
c.
percent concentration by mass
b.
molarity
d.
all of the above
 

72. 

Which of the following is expressed in grams of solute instead of moles of solute?
a.
molality
c.
neither a nor b
b.
molarity
d.
a and b
 

73. 

What is the molarity of a solution that contains 0.202 mol KCl in 7.98 L solution?
a.
0.0132 M
c.
0.459 M
b.
0.0253 M
d.
1.363 M
 

74. 

What is the molality of a solution that contains 5.10 mol KNO3 in 4.47 kg water?
a.
0.315 m
c.
1.02 m
b.
0.779 m
d.
1.14 m
 

75. 

What is the molarity of a solution that contains 125 g NaCl in 4.00 L solution?
a.
0.535 M
c.
8.56 M
b.
2.14 M
d.
31.3 M
 

76. 

What is the molality of a solution that contains 31.0 g HCl in 5.00 kg water?
a.
0.062 m
c.
0.170 m
b.
0.425 m
d.
15.5 m
 

77. 

How many moles of HCl are present in 0.70 L of a 0.33 M HCl solution?
a.
0.23 mol
c.
0.38 mol
b.
0.28 mol
d.
0.47 mol
 

78. 

The concentration of a water solution of NaCl is 2.48 m, and it contains 806 g of water. How much NaCl is in the solution?
a.
2.00 g
c.
117 g
b.
89.3 g
d.
224 g
 

79. 

An NaOH solution contains 1.90 mol of NaOH, and its concentration is 0.555 M. What is its volume?
a.
0.623 L
c.
1.05 L
b.
0.911 L
d.
3.42 L
 

80. 

What mass of water must be used to make a 1.35 m solution that contains 8.20 mol of NaOH?
a.
6.07 kg
c.
11.1 kg
b.
7.44 kg
d.
14.5 kg
 

81. 

How many milliliters water are needed to make a 0.171 M solution that contains 1.00 g of NaCl?
a.
100 mL
c.
171 mL
b.
1000 mL
d.
17.1 mL
 

Problem
 

82. 

A solution contains 85.0 g of NaNO3, and has a volume of 750. mL. Find the molarity of the solution.
 

83. 

What is the molarity of a solution of sucrose, C12H22O11, that contains 125 g of sucrose in 3.50 L of solution?
 

84. 

How many grams of NaOH are required to prepare 200. mL of a 0.450 M solution?
 

85. 

How many grams of NaC2H3O2 are needed to prepare 350. mL of a 2.75 M solution?
 

86. 

How many grams of Na2SO4 are needed to prepare 750. mL of a 0.375 M solution?
 

87. 

Iron(III) chloride can be produced by reacting Fe2O3 with a hydrochloric acid solution. How many milliliters of a 6.00 M HCl solution are needed to react with excess Fe2O3 to produce 16.5 g of FeCl3?
 

88. 

Muriatic acid is often used to remove rust. A solution of muriatic acid, HCl, reacts with Fe2O3 deposits on industrial equipment. How many liters of 5.50 M HCl would be needed to react completely with 439 g Fe2O3?
 



 
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